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    Crystal structure, spectroscopic (FT-IR, 1H and 13C NMR) characterization and density functional theory calculations on Ethyl 2-(dichloromethyl)-4-methyl-1-phenyl-6-thioxo-1,6-dihydropyrimidine-5-carboxylate
    (Elsevier, 2018) Pekparlak, A.; Tamer, O.; Kanmazalp, S. D.; Berber, N.; Arslan, M.; Avci, D.; Dege, N.
    A multicomponent reaction between ethyl 3-aminocrotonate, phenyl isothiocyanates, 2,2-dichloroacetyl chloride and to give 6-thioxo-1,6-dihydropyrimidine-5-carboxylate. This one-pot, three-component condensation took place under mild conditions in THF/CH3CN at 50 degrees C. The crystal structure of the synthesized molecule was elucidated by X-ray diffraction crystallography. The FT-IR, H-1 and C-13 NMR spectra for Ethyl 2-(dichloromethyl)-4-methyl-1-phenyl-6-thioxo-1,6-dihydropyrimidine-5-carboxylate have been experimentally recorded. The molecular geometry, vibrational frequencies and NMR chemical shifts for the title molecule have been calculated by using the B3LYP level of density functional theory method with 6-311++G(d,p) basis set. The obtained data demonstrated that DFT/B3LYP level can reproduce the experimental results. The computed vibrational frequencies provided a detailed assignment of molecular vibrations associated with each of the experimental bands observed. Additionally, nonlinear optical (NLO) properties and molecular electrostatic potential (MEP) have been evaluated by using B3LYP level in conjunction with 6-311++G(d,p) basis set. (C) 2018 Elsevier B.V. All rights reserved.
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    Health professionals' perception of social stigma and its relationship to compassion satisfaction, burnout, compassion fatigue, and intention to leave the profession during the COVID-19 pandemic
    (Routledge Journals, Taylor & Francis Ltd, 2022) Selcuk, K. Tari; Avci, D.; Atac, M.
    This study was conducted to investigate the relationship between health professionals' perception of social stigma, and compassion satisfaction, burnout, compassion fatigue and intention to leave the profession during the COVID-19 pandemic. This study is a descriptive online study. It was conducted with 420 health professionals working in a university hospital serving as a pandemic hospital in a province of Turkey. The study data were collected through an online questionnaire including the Personal Information Form, Social Stigma Perception Scale, Professional Quality of Life Scale, and Scale of Intentions to Leave the Profession. Social stigma perception was the negative predictor of compassion fatigue, and the positive predictor of burnout, compassion fatigue and intention to leave the profession.