Gonca, Ergun2025-01-272025-01-2720171060-13251520-5738https://doi.org/10.1080/10601325.2017.1309253https://hdl.handle.net/20.500.12428/21565The reaction of (5-hydroxypentylthio magnesium porphyrazine) with 2-methoxy-4,6-bis(trifluoromethyl)benzoic acid in DCCI and PTSA, esterified MgPz having [5-thiopentyl 2-methoxy-4,6-bis(trifluoromethyl)benzoate] substituent was obtained. Further reactions of the metal-free porphyrazine with M2+(Mg, Co, Cu, Zn, Fe) acetates have produced the metallo-porphyrazines. Finally, by the reaction of FePzCl with pyridine or pyrazine compounds, [FePz(py)(2)] and [FePz(pyz)](n) complexes were prepared as the novel stable complexes, respectively. The target compounds have been characterized by using different spectroscopic methods such as FT-IR, UV-Vis, mass, H-1, C-13, and F-19 NMR together with elemental analysis. The aggregation and the solubility features were indicated in various concentrations and solvents.eninfo:eu-repo/semantics/closedAccessPorphyrazine2-methoxy-4,6-bis(trifluoromethyl)benzoic acidesterificationbisaxial complexbridged complexArticle54958959710.1080/10601325.2017.1309253Q3WOS:0004141982000062-s2.0-85025121015Q2