Turkyilmaz, MuratBaran, YakupOzdemir, Namik2025-01-272025-01-2720112056-9890https://doi.org/10.1107/S1600536811015625https://hdl.handle.net/20.500.12428/28463In the title molecular salt, C17H17N5+center dot 2ClO(4), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)degrees, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.614 (8):0.386 (8) and 0.591 (7):0.409 (7). An intramolecular C-H center dot center dot center dot N contact occurs in the cation. In the crystal, the components are linked by N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds and pi-pi stacking interactions [centroid-centroid separation = 3.642 (3) angstrom].eninfo:eu-repo/semantics/openAccess2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate)Article67O1282U182110.1107/S1600536811015625N/AWOS:0002913085001552-s2.0-7995559075721754563N/A