Solmaz, Adnanİlter, ZülfiyeKaya, İsmet2022-08-112022-08-112021Solmaz, A., Ilter, Z., & İsmet, Kaya (2021). Synthesis, Characterization, Thermal Behavior, and Dielectric Properties of Methacrylate Polymers Containing Imine Bonding. Journal of Electronic Materials, 50(9), 5348–5358. https://doi.org/10.1007/s11664-021-09063-80361-52351543-186Xhttps://doi.org/10.1007/s11664-021-09063-8https://hdl.handle.net/20.500.12428/3666Two diferent Schif bases, viz. 1-{4-[(5-bromo-2-hydroxybenzyliden)amino]phenyl}ethanone (5-Br-2HBAPE) and 1-{4-[(4-hydroxybenzylidene)amino]phenyl}ethanone (4-HBAPE), have been prepared by condensation of 5-bromosalicylaldehyde and 4-hydroxybenzaldehyde with 4-aminoacetophenone in ethanol at molar ratio of 1:1. Then, Schif base methacrylate monomers, i.e., 2-(((4-acetylphenyl)imino)methyl)-4-bromophenylmethacrylate (APIMBPM) and 2-(((4-acetylphenyl)imino)methyl)phenylmethacrylate (APIMPM), were synthesized by reaction of each Schif base compound with methacryloylchloride at 0°C to 5°C. Schif base methacrylate polymers poly(APIMBPM) and poly(APIMPM) were then prepared by free-radical polymerization in tetrahydrofuran (THF) at 70°C using azobisisobutyronitrile (AIBN) as initiator. The structure of 5-Br-2HBAPE, 4-HBAPE, APIMBPM, APIMPM, poly(APIMBPM), and poly(APIMPM) was confrmed by Fourier-transform infrared (FT-IR) and 1 H and 13C nuclear magnetic resonance (NMR) spectroscopy. The thermal behavior of poly(APIMBPM) and poly(APIMPM) was studied by diferential scanning calorimetry (DSC) and thermogravimetry (TG). The glass-transition temperature (Tg) of poly(APIMBPM) and poly(APIMPM) was found to be 113°C and 108°C, respectively. The residual amount of poly(APIMBPM) and poly(APIMPM) at 1000°C was found to be 45.60% and 26.35%, respectively. Dielectric and conductivity measurements were carried out on the Schif base methacrylate polymers by impedance analysis as a function of frequency. The conductivity of poly(APIMBPM) and poly(APIMPM) was found to be 1.30 × 10−9 S cm−1 and 2.14 × 10−9 S cm−1, respectively. Scanning electron microscopy (SEM) was used to investigate the morphology of the Schif base methacrylate polymers, and their antimicrobial activity against bacteria and fungus was determined by disk difusion method. Poly(APIMBPM) exhibited good antibacterial property against Klebsiella pneumonia. Poly(APIMBPM) and poly(APIMPM) exhibited good antifungal action against Candida albicans. We thus describe the synthesis of diferent Schif base methacrylate polymers and their thermal behavior, electrical properties, and antimicrobial activities.eninfo:eu-repo/semantics/closedAccessFree Radical PolymerizationSchif Base PolymerThermal PropertiesDielectric FeaturesAntibacterial ActivityAntifungal ActivityArticle509/Special Issue SI5348535810.1007/s11664-021-09063-8Q3WOS:0006671154000012-s2.0-85111939359