Preparation and characterization of Co(II), Ni(II) and Cu(II) complexes of a ligand containing 1,3,4-thiadiazole groups

Ozturk, Omer FarukCansiz, AhmetKoparir, Metin2025-01-272025-01-2720070340-42851572-901Xhttps://doi.org/10.1007/s11243-006-0159-1https://hdl.handle.net/20.500.12428/20649(1R,2R)-1,2-bis-(5-amino-1,3,4-thiadiazole-2-yl)ethane-1,2-diol (L) has been prepared by the reaction of thiosemicarbazide with (2R,3R)-(+)-tartaric acid (I) and phosphorous oxychloride, and its complexes with Co(II), Ni(II) and Cu(II) have been obtained. The structures of the ligand and its complexes have been established by i.r., H-1- and C-13-n.m.r. spectra, u.v.-vis-nir spectroscopy, elemental analyses, T.g.-D.t.a. and magnetic susceptibility measurements.eninfo:eu-repo/semantics/closedAccess1,2-DiolsPreparation and characterization of Co(II), Ni(II) and Cu(II) complexes of a ligand containing 1,3,4-thiadiazole groupsArticle32222422710.1007/s11243-006-0159-1Q3WOS:0002448906000152-s2.0-33947159284Q2