Aydın, FatmaTunoğlu, NazanAykaç, DoğanArslan, Nahide BurcuKazak, Canan2025-01-272025-01-2720121300-05271303-6130https://search.trdizin.gov.tr/tr/yayin/detay/138584https://hdl.handle.net/20.500.12428/20024A novel artificial receptor, 1,1’-(naphthalene-1,8-diyl)-3,3’-dibenzoyl-bisthiourea, based on a 1,8-naphthalene skeleton bearing bisthiourea groups was prepared and characterized by IR and $^1H-NMR, ^13C-NMR$, and MS spectroscopic techniques. The compound proved to be an efficient and selective naked-eye detector for the fluoride, cyanide, and hydroxide ions in DMSO. The crystal structure of the title compound was examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P − 1 with the unit cell parameters: a = 8.1556(8) $\\AA$, b = 12.0127(11) $\\AA$, c = 13.2081(11) $\\AA$, α = 109.510(7) ◦ , β = 95.390(7)◦, γ = 103.660(7)◦ , Z = 2. The intramolecular N-H· · ·O hydrogen bondinginteractions between the N-H and the oxygen atom of C=O groups support a 1,1’-(naphthalene-1,8-diyl)- 3,3’-dibenzoyl-bisthiourea framework. Moreover, the combinations of N—H· · ·S bonds produce $R^2_2$ (8)rings.eninfo:eu-repo/semantics/openAccessKimyaOrganikArticle365764777138584