Bis{2,6-bis[1-(4-fluorophenylimino)ethyl]pyridine}-1?3N,N?,N;3?3N,N?,N-di-?-chlorido-1:2?2Cl:Cl;-2:3?2Cl:Cl-trichlorido-1?Cl,2?Cl,3?Cl-2-copper(I)-1,3-dicopper(II)

Ozdemir, NamikDincer, MuharremDayan, OsmanCetinkaya, Bekir2025-01-272025-01-2720082053-2296https://doi.org/10.1107/S0108270108012237https://hdl.handle.net/20.500.12428/26279The title complex, [Cu3Cl5(C21H17N3F2)(2)], is the first reported copper trimer including both Cu-I and Cu-II ions. The two Cu-II ions are five-coordinate in a significantly distorted square-pyramidal arrangement, with the bridging Cl atom located in the apical position, and the pyridine (py) N atom, the two imine N atoms and the other Cl atom located in the basal plane. The Cu-I ion is in a trigonal planar configuration surrounded by three Cl atoms. The structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi(py) hydrogen bonds.eninfo:eu-repo/semantics/closedAccessRuthenium(Ii) ComplexesEthylene PolymerizationCatalytic-ActivityLigandsCrystalBis{2,6-bis[1-(4-fluorophenylimino)ethyl]pyridine}-1?3N,N?,N;3?3N,N?,N-di-?-chlorido-1:2?2Cl:Cl;-2:3?2Cl:Cl-trichlorido-1?Cl,2?Cl,3?Cl-2-copper(I)-1,3-dicopper(II)Article64M224M22710.1107/S0108270108012237N/AWOS:0002564682000032-s2.0-4494926092818535329N/A