Sezgin, MeryemÖzay, ÖzgürKoyuncu, SermetOzay, HavaKoyuncu, Fatma Baycan2025-01-272025-01-2720151385-89471873-3212https://doi.org/10.1016/j.cej.2015.03.134https://hdl.handle.net/20.500.12428/24234In this work, a new phosphazene/carbazole hybride dendron (PC) was synthesized and then directly coated onto ITO glass surface to provide a dendritic polymer network, poly-(PC), by using potentiodynamic electrochemical process. Structure of dendron was identified by FT-IR, H-1 and P-31 NMR, and also TOF-MS analyses. The optical and electrochemical properties of PC and its electrochemical crosslinked product were investigated by using UV-vis absorption, fluorescence and CV techniques. A neutral, colorless electrochromic device was constructed in the sandwich configuration [indium tin oxide (ITO)coated glass/anodically coloring material (poly-(PC))//gel electrolyte//cathodically coloring material (PEDOT)/ITO-coated glass] and revealed a short response time (about 0.5 s), high coloration efficiency (981 cm(2) C-1) and high redox stability. (C) 2015 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessElectrochromic devicePhosphazeneCarbazoleDendronArticle27428228910.1016/j.cej.2015.03.134Q1WOS:0003554963000302-s2.0-84927728831Q1