Kolcu, FeyzaKaya, İsmet2025-01-272025-01-2720221878-53521878-5379https://doi.org/10.1016/j.arabjc.2022.103935https://hdl.handle.net/20.500.12428/26462This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).Carbazole-based Schiff base chemosensor was synthesized in one-pot synthesis using 2hydroxy-1-naphtaldehyde for fluorescent sensing of Al3+ ions. Characterization of the ligand (L) was revealed through spectroscopic and physicochemical techniques. The fluorescence emission responses of L to various metal ions and anions were investigated. The chelation was studied by UV-vis, 1H NMR, LC-MS/MS, fluorescence titration and Job's plot analysis. Bathochromic shift resulted from charge transfer from L to electrophilic Al3+ ion was observed in the chelation of L with Al3+. The potentiality of L to be a distinguished probe to detect Al3+ ions was due to a chelation enhanced fluorescence (CHEF) effect, concomitant with noticeable fluorescent enhancement. A significant fluorescence enhancement at 533 nm was observed in ethanol-water (1:1, v/v) solution upon addition of Al3+ along with a distinct color change from yellow to white. Non-fluorescent ligand exposed highly sensitive turn-on fluorescent sensor behavior for selectively sensing Al3+ ions via 1:1 (ligand:metal) stoichiometry. The ligand's specificity in the existence of other tested metal ions and anions indicated no observation in color change. The ligand-Al3+ complex formation was reversible upon addition of chelating agent EDTA. The ligand interacted with Al3+ ions with an association constant of Ka = 5 x 104 M-1. The limit of detection (LOD) was found to be 2.59 x 10-7 M. The synthesized Schiff base could efficiently detect Al3+ ions as a fluorescent sensor. (c) 2022 Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).eninfo:eu-repo/semantics/openAccessSchiff baseFluorescent chemosensorESIPTAl3+Job?s plotCHEF effectArticle15710.1016/j.arabjc.2022.103935Q2WOS:0008041910000092-s2.0-85129497067Q1