A comparative study of aminothiazole-based polymers synthesized by chemical oxidative polymerization

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridYıldırım, Mehmet / 0000-0001-9948-9106
dc.contributor.authorYıldırım, Mehmet
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:17:17Z
dc.date.available2025-01-27T20:17:17Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPoly(2-aminothiazole) derivatives were synthesized by chemical oxidative polymerization method using 2-aminothiazole (2AT), 2-aminobenzothiazole (2ABT) and 6-ethoxy-2-aminobenzothiazole (EtO-2ABT) as the monomers. Structural characterizations were carried out by Fourier Transform Infrared (FT-IR), nuclear magnetic resonance (NMR), size exclusion chromatography (SEC), and scanning electron microscopy (SEM) techniques. The synthesized polymers were investigated by the means of solubility tests, UV-vis, spectrofluorometry, cyclic voltammetry (CV), thermogravimetry-differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), and dynamical mechanical analysis (DMA) techniques. Solid state electrical conductivities were also measured on the polymer films. Phenyl attached aminothiazole polymers had higher solubilities than the unsubstituted poly(2-aminothiazole). The polymers had lower band gaps than the corresponding monomers indicating their polyconjugated structures. P-2AT and P-2ABT emitted bluish light under UV irradiation while P-EtO-2ABT emitted red color with lower intensity. Phenyl attachment and ethoxy substitution of the monomer caused production of polymer with higher thermal stability. Additionally, a discussion of electrical conductivities and morphological variations was reported. (C) 2012 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2012.01.010
dc.identifier.endpage443
dc.identifier.issn0379-6779
dc.identifier.issue5-6
dc.identifier.scopus2-s2.0-84856990462
dc.identifier.scopusqualityQ1
dc.identifier.startpage436
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2012.01.010
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21536
dc.identifier.volume162
dc.identifier.wosWOS:000302978500005
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectThiazole polymers
dc.subjectConjugated polymers
dc.subjectFluorescence
dc.subjectThermal analysis
dc.titleA comparative study of aminothiazole-based polymers synthesized by chemical oxidative polymerization
dc.typeArticle

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